Communication: IR spectroscopy of neutral transition metal clusters through thermionic emission
نویسندگان
چکیده
منابع مشابه
IR spectroscopy of neutral transition metal clusters through thermionic emission
emission Vivike J. F. Lapoutre, Marko Haertelt, Gerard Meijer, André Fielicke, and Joost M. Bakker a) FOM Institute for Plasma Physics Rijnhuizen, Edisonbaan 14, NL-3439 MN Nieuwegein, The Netherlands Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, D-14195 Berlin, Germany Radboud University Nijmegen, Institute for Molecules and Materials, FELIX Facility, Toernooiveld 7, 6525 E...
متن کاملCommunication: IR spectroscopy of neutral transition metal clusters through thermionic emission.
The resonant multiple photon excitation of neutral niobium clusters using tunable infrared (IR) radiation leads to thermionic emission. By measuring the mass-resolved ionization yield as a function of IR wavenumber species selective IR spectra are obtained for Nb(n) (n = 5-20) over the 200-350 cm(-1) spectral range. The IR resonance-enhanced multiple photon ionization spectra obtained this way ...
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We report experimental infrared spectra of neutral metal clusters in the gas phase. Multiple photon dissociation of the argon complexes of niobium clusters is used to obtain vibrational spectra in the 80-400 cm(-1) region. The observed spectra for Nb(9)Ar(n) (n=1-4) are different for different values of n. This is explained by the presence of two isomers of Nb(9) that have different affinities ...
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Introduction Thermionic cathodes are used in many industrial vacuum electronic applications. Vacuum tubes for high-frequency or high-power applications are one example (e.g., see [1]). The emission properties of thermionic electron sources in vacuum devices are often Bimproved[ by the addition of oxide coatings on the metal cathode surface [2, 3]. The explanation of the improvement is usually b...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2013
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.4822324